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      3652-89-9 structure, C12H8BrN
      4-Bromo-9H-carbazole
      CAS No.: 3652-89-9 Formula: C12H8BrN Molecular Weight: 246.10300
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      4-Bromo-9H-carbazole

      CAS No.:

      3652-89-9

      Formula:

      C12H8BrN

      Molecular Weight: 246.10300
      Suppliers: All (42) China Suppliers (39) Price Available (3) Contractor (3)

      Basic Info

      Chemical Name

      4-Bromo-9H-carbazole

      Synonyms

      4-Brom-butyroylbromid; 4-bromo-butyryl bromide; 4-Brom-carbazol; 4-Brom-butyrylbromid; 4-bromo-carbazole; Butanoyl bromide,4-bromo; Expand

      CAS No.

      3652-89-9

      Molecular Formula

      C12H8BrN

      Molecular Weight

      246.10300

      PSA

      15.79000

      LogP

      4.08360

      Safety Info

      HS Code

      2933990090

      SDS 1.0

      Expand

      SDS 1.0

      Collapse
      Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

      SAFETY DATA SHEETS

      According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

      Version: 1.0

      Creation Date: Aug 15, 2017

      Revision Date: Aug 15, 2017

      1.Identification

      1.1 GHS Product identifier

      Product name 4-Bromo-9H-carbazole

      1.2 Other means of identification

      Product number -
      Other names 4-Brom-butyroylbromid

      1.3 Recommended use of the chemical and restrictions on use

      Identified uses For industry use only.
      Uses advised against no data available

      1.4 Supplier's details

      Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
      Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
      Xuhui District, Shanghai, China
      Telephone +86(21)64956998
      Fax +86(21)54365166

      1.5 Emergency phone number

      Emergency phone number +86-400-6021-666
      Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

      2.Hazard identification

      2.1 Classification of the substance or mixture

      Skin irritation, Category 2

      Eye irritation, Category 2

      2.2 GHS label elements, including precautionary statements

      Pictogram(s)
      Signal word

      Warning

      Hazard statement(s)

      H315 Causes skin irritation

      H319 Causes serious eye irritation

      Precautionary statement(s)
      Prevention

      P264 Wash ... thoroughly after handling.

      P280 Wear protective gloves/protective clothing/eye protection/face protection.

      Response

      P302+P352 IF ON SKIN: Wash with plenty of water/...

      P321 Specific treatment (see ... on this label).

      P332+P313 If skin irritation occurs: Get medical advice/attention.

      P362+P364 Take off contaminated clothing and wash it before reuse.

      P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

      P337+P313 If eye irritation persists: Get medical advice/attention.

      Storage

      none

      Disposal

      none

      2.3 Other hazards which do not result in classification

      none

      3.Composition/information on ingredients

      3.1 Substances

      Chemical name Common names and synonyms CAS number EC number Concentration
      4-Bromo-9H-carbazole 4-Bromo-9H-carbazole 3652-89-9 none 100%

      4.First-aid measures

      4.1 Description of necessary first-aid measures

      General advice

      Consult a physician. Show this safety data sheet to the doctor in attendance.

      If inhaled

      If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

      In case of skin contact

      Wash off with soap and plenty of water. Consult a physician.

      In case of eye contact

      Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

      If swallowed

      Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

      4.2 Most important symptoms/effects, acute and delayed

      no data available

      4.3 Indication of immediate medical attention and special treatment needed, if necessary

      no data available

      5.Fire-fighting measures

      5.1 Extinguishing media

      Suitable extinguishing media

      Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

      5.2 Specific hazards arising from the chemical

      no data available

      5.3 Special protective actions for fire-fighters

      Wear self-contained breathing apparatus for firefighting if necessary.

      6.Accidental release measures

      6.1 Personal precautions, protective equipment and emergency procedures

      Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

      6.2 Environmental precautions

      Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

      6.3 Methods and materials for containment and cleaning up

      Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

      7.Handling and storage

      7.1 Precautions for safe handling

      Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

      7.2 Conditions for safe storage, including any incompatibilities

      Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

      8.Exposure controls/personal protection

      8.1 Control parameters

      Occupational Exposure limit values

      no data available

      Biological limit values

      no data available

      8.2 Appropriate engineering controls

      Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

      8.3 Individual protection measures, such as personal protective equipment (PPE)

      Eye/face protection

      Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

      Skin protection

      Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

      Respiratory protection

      Wear dust mask when handling large quantities.

      Thermal hazards

      no data available

      9.Physical and chemical properties

      Physical state no data available
      Colour no data available
      Odour no data available
      Melting point/ freezing point no data available
      Boiling point or initial boiling point and boiling range no data available
      Flammability no data available
      Lower and upper explosion limit / flammability limit no data available
      Flash point no data available
      Auto-ignition temperature no data available
      Decomposition temperature no data available
      pH no data available
      Kinematic viscosity no data available
      Solubility no data available
      Partition coefficient n-octanol/water (log value) no data available
      Vapour pressure no data available
      Density and/or relative density no data available
      Relative vapour density no data available
      Particle characteristics no data available

      10.Stability and reactivity

      10.1 Reactivity

      no data available

      10.2 Chemical stability

      Stable under recommended storage conditions.

      10.3 Possibility of hazardous reactions

      no data available

      10.4 Conditions to avoid

      no data available

      10.5 Incompatible materials

      no data available

      10.6 Hazardous decomposition products

      no data available

      11.Toxicological information

      Acute toxicity

      • Oral: no data available
      • Inhalation: no data available
      • Dermal: no data available

      Skin corrosion/irritation

      no data available

      Serious eye damage/irritation

      no data available

      Respiratory or skin sensitization

      no data available

      Germ cell mutagenicity

      no data available

      Carcinogenicity

      no data available

      Reproductive toxicity

      no data available

      STOT-single exposure

      no data available

      STOT-repeated exposure

      no data available

      Aspiration hazard

      no data available

      12.Ecological information

      12.1 Toxicity

      • Toxicity to fish: no data available
      • Toxicity to daphnia and other aquatic invertebrates: no data available
      • Toxicity to algae: no data available
      • Toxicity to microorganisms: no data available

      12.2 Persistence and degradability

      no data available

      12.3 Bioaccumulative potential

      no data available

      12.4 Mobility in soil

      no data available

      12.5 Other adverse effects

      no data available

      13.Disposal considerations

      13.1 Disposal methods

      Product

      The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

      Contaminated packaging

      Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

      14.Transport information

      14.1 UN Number

      ADR/RID: no data available IMDG: no data available IATA: no data available

      14.2 UN Proper Shipping Name

      ADR/RID: no data available
      IMDG: no data available
      IATA: no data available

      14.3 Transport hazard class(es)

      ADR/RID: no data available IMDG: no data available IATA: no data available

      14.4 Packing group, if applicable

      ADR/RID: no data available IMDG: no data available IATA: no data available

      14.5 Environmental hazards

      ADR/RID: no IMDG: no IATA: no

      14.6 Special precautions for user

      no data available

      14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

      no data available

      15.Regulatory information

      15.1 Safety, health and environmental regulations specific for the product in question

      Chemical name Common names and synonyms CAS number EC number
      4-Bromo-9H-carbazole 4-Bromo-9H-carbazole 3652-89-9 none
      European Inventory of Existing Commercial Chemical Substances (EINECS) Not Listed.
      EC Inventory Not Listed.
      United States Toxic Substances Control Act (TSCA) Inventory Not Listed.
      China Catalog of Hazardous chemicals 2015 Not Listed.
      New Zealand Inventory of Chemicals (NZIoC) Not Listed.
      Philippines Inventory of Chemicals and Chemical Substances (PICCS) Not Listed.
      Vietnam National Chemical Inventory Not Listed.
      Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Not Listed.

      16.Other information

      Information on revision

      Creation Date Aug 15, 2017
      Revision Date Aug 15, 2017

      Abbreviations and acronyms

      • CAS: Chemical Abstracts Service
      • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
      • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
      • IMDG: International Maritime Dangerous Goods
      • IATA: International Air Transportation Association
      • TWA: Time Weighted Average
      • STEL: Short term exposure limit
      • LC50: Lethal Concentration 50%
      • LD50: Lethal Dose 50%
      • EC50: Effective Concentration 50%

      References

      • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
      • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
      • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
      • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
      • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
      • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
      • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
      • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
      • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

      Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
      1H NMR : PredictExpand

      NMR Spectrum 1H NMR : Predict

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      3652-89-9 NMR spectrum
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